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Authors: David Feldman
Will
Super Glue Stick to Teflon?
We were wary of contacting Loctite and Teflon about this almost metaphysical Imponderable, for it would be like prying a confession from the immovable object (Teflon) and the unstoppable force (Super Glue) that one of their reputations was seriously exaggerated. But we are worldly wise in such matters. After all, we had already cracked the centuries-old conundrum about “If nothing sticks to Teflon, how do they get Teflon to stick to the pan?” in
Why Do Clocks Run Clockwise?
We were ready for a new challenge.
So first we contacted Du Pont, the chemical giant that markets Teflon, a registered trademark for polytetrafluoroethylene (which, for obvious reasons, we’ll call ptfe). As we expected, Kenneth Leavell, research supervisor for Du Pont’s Teflon/Silverstone division, took a hard line. He firmly holds the conviction that Super Glue won’t stick to Teflon, at least “not very well and certainly not reliably.” Here are some of the reasons why not:
1. The combination of fluorine and carbon in ptfe forms one of the strongest bonds in the chemical world and one of the most stable.
2. The fluorine atoms around the carbon-fluorine bond are inert, so they form an “impenetrable shield” around the chain of carbon atoms, keeping other chemicals from entering. As Leavell puts it,
Adhesives need to chemically or physically bond to the substrate to which they are applied. Ptfe contains no chemical sites for other substances to bond with.
3. As we just learned with glue bottles, adhesives need to wet the substrate directly or creep into porous areas in the substrate. But the low surface energy of ptfe prevents wetting and bonding. Leavell compares it to trying to get oil and water to stick together.
And then he lays down the gauntlet:
Super Glue is “super” because of its speed of cure and relatively strong bonds. As an adhesive for ptfe, it’s no better than epoxies, polyurethanes, etc., would be.
So, the immovable object claims near invincibility. How would the unstoppable force react? We contacted Loctite’s Richard Palin, technical service adviser. And he folded like a newly cleaned shirt. Yes, Palin admitted, Teflon lacks the cracks necessary for Super Glue to enter in order to bond properly; there would be nowhere for the glue to get into the pan. Yes, he confessed, the critical surface tension is too low for the adhesive to wet the surface. Yes, he broke down in sobs, Super Glue would probably just bead up if applied to a Teflon pan.
Just kidding, actually. Palin didn’t seem upset at all about Super Glue’s inability to stick to Teflon. By all accounts, there doesn’t seem to be much demand for the task.
Submitted by Bill O’Donnell of Eminence, Missouri
.
Why
Do Many Women’s Fingernails Turn Yellow After Repeated Use of Nail Polish?
Chances are, the culprit is one of two types of ingredients contained in all nail polish:
1.
Nitrous cellulose
. Nitrous cellulose is wood pulp treated with acids; it provides the hardness necessary to make polish stay on your nail plate. As a senior chemist from a major cosmetics company told us: When the moisture from polish dries, all you are left with is nitrous cellulose and pigment.
When nitrous cellulose breaks down, nitric acid forms. Nitric acid attacks the proteins in the nail and turns the nail yellow. The yellowing occurs only on the top layers of the nail plate and will eventually fade away if more acids aren’t applied.
2.
Preservatives
. Tolulene-sulfonimide and formaldehyde are part of the base coat of nail polishes and are used as preservatives. According to dermatologist Jerome Litt, of Beachwood, Ohio, formaldehyde resin can turn keratin (the tough, fibrous protein that is the principal constituent in nails) yellow.
But don’t assume that yellow nails are necessarily caused by the chemicals in nail-care products (or other, noncosmetic chemicals, such as inks, shoe polishes, and dyes, which can also stain nails yellow). Many heavy smokers, for example, have yellow nails. Even the ingredients in some orally administered pharmaceuticals can stain nails.
Physicians often examine fingernails to help determine the general health of patients, for many illnesses are betrayed by yellowing. The most common noncosmetics cause of yellowed nails is a yeast or other type of fungus infection underneath the nail plate. But many other, more serious illnesses can occasionally be diagnosed when a physician spots yellow nails, including diseases of the lymphatic system, thyroid, chronic respiratory disease, diabetes, and certain liver and kidney diseases.
Other maladies are tipped off by different-colored nails. If the normal Caucasian nail looks pink, because of the ample blood supply to the nail bed underneath the nail plate, it can turn white when a person is anemic, and blue if the patient is suffering from heart or lung disease and insufficient oxygen is sent to the nail bed.
Now that we’ve scared you sufficiently, we’ll remind you that nail polish is much more likely to cause the discoloration than the illnesses we’ve chronicled above.
Submitted by Barbara Forsberg of Ballston Spa, New York
.
Why
Are Most Corrugated Boxes from Japan Yellow?
Unless it is bleached, the color of a box will be the color of its main material source—the wood that is turned into pulp fiber. In Japan (and China), the most plentiful source of fiber is straw, which has a yellow color, whereas North America’s main source for pulp is tannish trees.
Robert H. Gray, vice-president of the corrugated division of Old Dominion Box Company, told
Imponderables
that demand for paper is so great that most countries turn to local fiber sources that can be “easily grown and harvested in volume.” Corrugated boxes often contain recycled fibers besides wood, and Japanese boxes tend to have a higher percentage of recycled material in their pulp, both for ecological reasons and because straw fibers are weaker than wood fibers and bond less effectively.
As a result, the natural shade of Japanese boxes is more variable than our reliably colored kraft tan boxes. We don’t know whether the yellowish tinge of straw is what motivated Japanese boxmakers to dye their boxes yellow, but that is indeed what they do, as James F. Nolan, vice-president of the Fibre Box Association, explains:
The paper used in Asia for corrugated boxes is primarily recycled—with highly mixed sources of waste paper. In order to provide a uniform color for good print quality, the paper for the outer sheet of the corrugated board must be dyed.
Not that American boxes are beyond dye jobs. Although tan boxes are not dyed, liner-board white boxes are, according to Jim Boldt, of corrugated container giant Great Northern.
One glimpse of what undyed paper might look like was supplied by Karl Torjussen, of Westvaco. He asked us if we could think of the color of the cardboard backing on legal pads. “Sure,” we responded, “sort of a dishwater gray.”
That gray is the
natural
, undyed color of newsprint that has
not
been de-inked. No one cares too much what the back of a legal pad looks like, but we might find a stack of gray boxes utterly depressing—which is why, if boxes are made out of mostly recycled material, we dye them white and Asians dye them yellow.
Submitted by Kirk Baird of Noblesville, Indiana
.
Why
Are Covered Bridges Covered?
We have driven by stretches of rivers where, it seemed, about every third bridge we passed was a covered bridge. Why is one covered when the next two are topless?
The most obvious advantage to a covered bridge is that it blocks “the elements,” particularly snow. Accumulated snow can render a bridge impassable, and it is true that covered bridges are found most often in cold climates. Of course, one could argue that engineers should design covers for all roadways. But as we learned in
Do Penguins Have Knees?
(ah, but have we retained it?), bridges remain frozen long after adjacent road surfaces, primarily because bridge surfaces are exposed to the elements from all sides, the bottom as well as the top.
But then some folks believe that covered wooden bridges were originally constructed to ease the fears of horses, who were skittish about crossing bridges, particularly if they saw torrents of water gushing below. The fact that covered bridges resembled wooden barns supposedly also allayed the horses’ anxiety.
This question is reminiscent of one of our chestnut-Imponderables: Why do ranchers hang boots upside-down on fenceposts? The most likely answer is the same for both: to save wood from rotting. Alternate cycles of rain and sun play havoc on the wood. According to Stanley Gordon, of the Federal Highway Administration’s Bridge Division, an uncovered wooden bridge might last twenty years, while a covered bridge can last a century or longer.
Submitted by Gary L. Horn of Sacramento, California. Thanks also to Matthew Huang of Rancho Palos Verdes, California
.
How
Do Waiters and Waitresses Get Their Tip Money When the Gratuity Is Placed on a Credit Card?
Let’s look at the life cycle of a credit card transaction at a restaurant:
1. You get the bill. You pull out your trusty credit card and hand it to the waiter.
2. In most restaurants, the waiter or other employee must authorize the charge. In all but small restaurants, this authorization is now done electronically, and increasingly, a “record of charge” is printed out automatically displaying the food, liquor, and tax charges. Some restaurants still use the old-fashioned “chit,” in which the amounts must be entered by pen.
3. Conveniently (for the wait staff, anyway), a gaping space is left for “gratuity,” and the total amount of the bill is left empty.
4. The waiter also puts his name or ID code on the record of charge (this is the strange, unidentifiable number often put in a box toward the bottom of credit card chits).
5. If the charge has been approved, the waiter brings the paperwork back to the customer.
This is the point at which many diners have no idea what to do. For some reason, the myth persists that waiters do not want you to charge their gratuity. Walter Sanders, director of corporate affairs for Citicorp Diners Club (Citicorp bought Diners Club in 1980), phrased the dilemma so charmingly that we are allowing him a blatant plug:
My dad is one of those people so concerned about waiters and waitresses getting their tips that even when he charges a meal (on the Diners Club Card, of course) he still painstakingly digs for a
cash
tip, which he leaves under the coffee saucer.
Well, your readers—and my dad—can now rest assured that waitpeople everywhere get their full tips, in cash, even when those tips are put on the Diners Club Card.
6. Let’s assume the customer does pay the gratuity using a credit card. When the restaurant closes, the night’s proceeds are tabulated, and the waiter is paid on the spot, in cash (some restaurants pay on a weekly basis). The ID number of the waiter is used to identify his share of the gratuity money (although some restaurants pool tips). According to Melissa A. Bertelsen, of First Data Resources,
most merchants have Electronic Data Capture devices that will allow the merchant to enter the amount of the ticket and tip. The device will then break out the tip by waiter number and total his amount in tips for the evening.